Dichlorido[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN 3)methane]cobalt(II) monohydrate
نویسندگان
چکیده
In the title compound, [CoCl(2)(C(13)H(20)N(4))]·H(2)O, the Co(II) atom lies on a mirror plane and is four-coordinated by two N atoms of the imidazole ligand and two Cl atoms in a distorted tetra-hedral arrangement. The water mol-ecule participates in the formation of hydrogen bonds, resulting in a three dimensional network involving the Cl atoms and the NH groups. The terminal C atom of the ethyl group is disordered over two sites of equal occupancy.
منابع مشابه
Bis[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-κN 3)methane](nitrato-κ2 O,O′)nickel(II) nitrate
In the title compound, [Ni(NO(3))(C(13)H(20)N(4))(2)]NO(3), the Ni(II) ion shows a distorted octa-hedral geometry formed by four N atoms from two bis-(2-ethyl-5-methyl-1H-imidazol-4-yl)methane ligands and two O atoms from a chelating nitrate anion. Three ethyl groups in the complex cation and the O atoms of the uncoordinated nitrate anion are disordered over two sets of positions [occupancy rat...
متن کاملBis(nitrato-κO)bis[4,4,5,5-tetramethyl-2-(5-methyl-1H-imidazol-4-yl-κN 3)-2-imidazoline-1-oxyl 3-oxide-κO]nickel(II)
In the centrosymmetric mononuclear title complex, [Ni(NO(3))(2)(C(11)H(17)N(4)O(2))(2)], the Ni(II) atom displays a distorted octa-hedral coordination geometry and is six-coordinated by two N,O-bidentate nitronyl nitroxide radical ligands and two monodentate nitrate anions.
متن کاملDiaquabis[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN 3)nicotinato-κN]manganese(II)
In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol-ecules in a distorted octa-hedral environment. Inter-molecular O-H⋯O hydrogen bonds lead to a chain along [010]. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds are observed.
متن کامل{N-[1-(1H-Benzimidazol-2-yl)ethylidene-κN 3]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra-hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl-idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter-molecular benzimidazole-imidazole N-H⋯N hydrogen bonds link the mol-ecules into helical chains along the b-axis direction and C-H⋯Br hydrogen bonds link these chain...
متن کاملPoly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ2 N 3:N 3′](μ-5-methylisophthalato-κ2 O 1:O 3)cobalt(II)]
In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methyl-isophthalate bivalent anions and two N atoms from two different 1,4-bis-(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetra-hedral coordination geometry. Each 5-methyl-isophthalate ligand acts as a μ(2)-bridge, linking two Co(II...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011